邢唷> 欹e 鳵ObjbjJ袹2Z(籣b(籣b & & 8li4+zpW,*******$.06**4]+"""*"*""r~)T)爸p喼 <)~*s+0+) 1! 1) 1)"**"+ 1& Q w: 貧I{鄀:gSf[Advanced inorganic chemistry Ye^薔蛜 Faculty  Jun LUF枦Q Professor, PhD Affiliation: College of Science Work Phone: +86-10-64442146 E-mail:  HYPERLINK "mailto:wenlx@mail.buct.edu.cn" lujun@mail.buct.edu.cn Research Field: Inorganic Materials Chemistry: Optical and electric functionization of supramolecular intercalation assembly materials. Design and construction of novel inorganic photocatalyts/ photoelectrocatalysts and their performance study. Design and application study on novel inorganic/organic composite luminescence materials. Design and performance study on novel inorganic photovoltaic/energy storage materials.Education September, 1994 June, 1998: University of Science and Technology of China, Bachelor in Science September, 1998 June, 2004: University of Science and Technology of China, Ph.D. in ScienceWork Experience July, 2005 - June,2007: Postdoc Department of Chemistry, Hongkong University July, 2007 December, 2010: Associate Professor College of Science, Beijing University of Chemical Technology January, 2011 now: Professor College of Science, Beijing University of Chemical TechnologyRepresentative PublicationsJingjing Shi, Shuangde Li, Fengming Wang, Yanmei Li, Lina Gao, Xiaorang Zhang and Jun Lu*. In situ topotactic fabrication of direct Z-scheme 2D/2DZnO/ZnxCd1"xS single crystal nanosheet heterojunction for efficient photocatalytic water splitting. Catal. Sci. Technol, 2018, 8, 6458. Ping Zhang, Yuehua Hu, Ruili Ma, Ling Li, and Jun Lu*. Enhanced Green Fluorescence Protein/Layered Double Hydroxides Composite Ultrathin film: Bio-hybrid Assembly and its Potential Application as a Fluorescent Biosensor.J. Mater. Chem. B 2017, 5, 160. Yumei Qin, Jingjing Shi, Xianggeng Gong, Zeyun Tian, Ping Zhang and Jun Lu*.A Luminescent Inorganic/Organic Composite Ultrathin Film Based on a 2D Cascade FRET Process and Its Potential VOC Selective Sensing Properties. Adv. Funct. Mater. 2016, 26, 6752. Shufang Zheng, J. Lu* X. Duan.An inexpensive co-intercalated layered double hydroxide composite with electron donor-acceptor character for photoelectrochemical water splitting.Sci. Rep, 2015, 5, 12170. Zhen Li, Jun Lu*, Yumei Qin, Shuangde Li and Shenghui Qin.Two dimensional restriction-induced luminescence of tetraphenyl ethylene within the layered double hydroxide ultrathin films and its爁luorescence resonance energy transfer.J. Mater. Chem.燙,2013,1, 5944 Zhen Li ,燡un Lu*, Shuangde Li , Shenghui Qin ,and Yumei Qin.Orderly Ultrathin Films Based on Perylene/Poly(燦-vinylcarbazole) Assembled with Layered Double Hydroxide Nanosheets: 2D Fluorescence Resonance Energy Transfer and Reversible Fluorescence Response for Volatile Organic Compounds.Adv. Mater.2012,24, 6053. Dongpeng Yan,燡un Lu*,燤in Wei,*燚avid G. Evans, and Xue Duan.Layered Host-Guest Materials with Reversible燩iezochromic Luminescence.Angew. Chem. Int. Ed.2011,50, 7037. Dongpeng Yan,燡un Lu*, Jing Ma, Min Wei*, David G. Evans, and Xue Duan. Reversible燭hermal燬ensitive燜luorescent燯ltrathin燜ilm燘ased爋n燬upra-molecular燗rchitectures. Angew. Chem. Int. Ed.2011, 50, 720. Shuangde Li,燡un Lu*, Min Wei, David G. Evans, Xue Duan.Tris(8-hydroxyquinoline-5-sulfonate)aluminum Intercalated Mg朅l Layered Double Hydroxide with Blue Luminescence by Hydrothermal Synthesis. Adv. Funct. Mater.2010, 20, 2848. Dongpeng Yan,燡un Lu*, Min Wei*, Jingbin Han, Jing Ma, Feng Li, David G. Evans, and Xue Duan.Poly(p-phenylene) Anionic Derivative/Layered Double Hydroxides Ordered Ultra Thin Films with Blue Luminescence by Layer-by-layer Assembly. Angew. Chem. Int. Ed.2009, 48, 3073. z薔蛜 About Course This course is mostly established for foreign MS students and it will be taught in English. It is also applicable to those Chinese MS students who are eager to improve their international perspective, fundamental knowledge in current inorganic chemistry and communication skills in English. The objectives of this course are to help students understand the fundamental theories and knowledge of the current inorganic chemsitry, i.e., molecular symmetry, coordination chemistry, organometallic chemistry, cluster chemistry, supramolecular chemistry, solid inorganic chemistry and bioinorganic chemistry and to train skills for analyzing, understanding and solving related science problems of current chemistry research. Furthermore, this course was aimed to broaden the science horizon of MS students to grasp the interdisciplinary and pan-molecular feature of current inorganic chemistry.Outlines: 1. Introduction (2 hour) 2. Molecular symmetry and point groups(6 hour) 3. Coordination Chemistry (4 hours) 4. Organometallic Chemistry (8 hours) 5. Cluster chemistry (4 hours) 6. Supramolecular chemistry (8 hours) 7. Inorganic Solid State Chemistry (4 hours) 8. Bioinorganic chemistry (8 hours) z'Y瞺 Syllabus Instructor: Jun Lu, Yufei Song Dr./Prof. Course Code: Hours: 48 Credits: 3.0 Prerequisites: General Chemistry, Inorganic Chemistry Description: The objectives of this course are to help students understand the fundamental theories and knowledge of the fundamental theories and knowledge of the current inorganic chemsitry, molecular symmetry, coordination chemistry, organometallic chemistry, cluster chemistry, supramolecular chemistry, solid inorganic chemistry and bioinorganic chemistry and to train skills for analyzing, understanding and solving related science problems of current chemistry research.Textbook: Gary L.Miessler, Donald ATarr, 0Inorganic Chemistry 03rd Edition, Higher Education Press, China, 2006 References 1.F. Albert Cotton, Sir Geoffrey Wilkinson, Advanced Inorganic Chemistry, 3rd Edition, John Wiley & Sons, Inc. Germany, 1972 ; 2. Wai-Kee Li, Gong-Du Zhou, Thomas Mak Star Advanced Structural Inorganic Chemistry, Oxford University Press, USA, Inc. 2008; 3. R. John Errington, Advanced Practical Inorganic and Metalorganic Chemistry, Inc, 1997. General Syllabus: 1. Introduction (2 hour) Introduction of the history, current status, frontier and characteristics of inorganic chemistry; Recommend the related inorganic chemistry journals, and the teaching arrangements and the specific requirements.2. Molecular symmetry and point groups (6 hour) Description of the five kinds of independent symmetry operations and elements; The concepts of the point group and group, and their basic properties; Introduction of the simple application of group theory in inorganic chemistry.3. Coordination Chemistry (4 hours) The basic theory of coordination bonds, stereoisomerism, reaction mechanism and kinetics characteristics of coordination compounds; Some new functional coordination compounds.4. Organometallic Chemistry (8 hours) The basic concept, ligand types and bonding met F^`bdjlprvxz|  " x z 曛肆瓰崬崬崬崀p~p~p~p^L^~L^pL"h(CJOJQJ^JaJmH sH #jh(CJOJQJU^JaJh(CJOJQJ^JaJh(CJOJQJ^JaJo( h(5丆JOJQJ^JaJo(h(5丆JOJQJ^JaJ&jh(5丆JOJQJU^JaJhPg5丅*phv<hPg5丅*o(phv<&h(5丅*CJOJQJ^JaJph)h/5丅*CJOJQJ^JaJo(phF`z  ] $ { |  I J Z 勑`勑 刾剱鱚刾`剱 刾刞鷁刾`刞 刾剱鱚刾`剱 & F 8 & F$a$  & FWDgdPg$a$  - Q ] # $ z |    5 6 屙屙屙鑲工搫搫搫搫怵怵怵鈩搫搫搫mW*h(CJOJQJ^JaJmH nHsH tH-h(CJOJQJ^JaJmH nHo(sH tHh(5丆JOJQJ^JaJ h(5丆JOJQJ^JaJo((h(5>*CJOJQJ^JaJmH sH +h(5>*CJOJQJ^JaJmH o(sH %h(>*CJOJQJ^JaJmH sH h(CJOJQJ^JaJh(CJOJQJ^JaJo("6 7 8 = A H I J Z ^ c d g p q r y z    ! " & ) + ? 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Cluster chemistry (4 hours) Definition and structure features of atomic cluster compounds; Polyhedral skeletal electron-pair theory of borane structure; Types and characteristics of metal-metal bonds; Structure theory of the metal atom clusters; Properties and applications of various kinds of atomic cluster compounds.6. Supramolecular chemistry (8 hours) Basic concepts of supramolecular chemistry, molecular recognition, molecular assembly and molecular devices; Structures and properties of the three generations of organic host compounds; Supramolecular systems based on inorganic host compounds and typical molecular devices system.7. Inorganic Solid State Chemistry (4 hours) Basic concepts of point defect, chemical equilibrium of defect, non-stoichiometric compound and solid phase chemical reactions; Classification and features of point defect and basic types of the crystalline defect; Characteristics and mechanism of solid phase reaction. 8. Bioinorganic chemistry (8 hours) Bioinorganic chemistry has made remarkable progress in recent years. On the basis of introducing the structure and properties of biological macromolecules and studying the physical and chemical methods of biological macromolecules, this chapter focuses on the metal enzymes and protein systems containing iron, zinc, copper, molybdenum and nickel and their simulation studies. Grading: Project 20%; Homework 30%; Final exam 50%. 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